Facilitated inversion complicates the stereodynamics of an S<sub>N</sub>2 reaction at nitrogen center
نویسندگان
چکیده
Multiple-inversion, the analogue of double-inversion pathway recently revealed for SN2@C, is key mechanism in SN2 at N center undermining stereospecificity.
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2021
ISSN: ['2041-6520', '2041-6539']
DOI: https://doi.org/10.1039/d1sc00490e